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Polyhedral oligomeric silsesquioxane bound fulleropyrrolidines

✍ Scribed by David J. Clarke; Janis G. Matisons; George R. Simon; Marek Samoc; Anna Samoc

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
157 KB
Volume
22
Category
Article
ISSN
0268-2605

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## Abstract Polyhedral oligomeric silsesquioxane (POSS) cages containing an iminofullerene species are reported herein. Monosubstituted benzyl chloride POSS was synthesized, and subsequently reacted with sodium azide to form mono benzyl azide POSS. The azide was subsequently reacted with C~60~ in a

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A diverse and entirely new class of monomer and polymer technology based on polyhedral oligomeric silsesquioxane (POSS) reagents has been developed. POSS reagents are unique in that they are physically large (approx. 15 A ˚diameter and 1000 amu) and are composed of a robust silicon-oxygen framework

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## Abstract Polyhedral oligomeric silsesquioxane (POSS) polymers were synthesized by the dehydrogenative condensation of (HSiO~3/2~)~8~ with water in the presence of diethylhydroxylamine followed by trimethylsilylation. Coating films were prepared by spin‐coating of the coating solution prepared by

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## Abstract All siloxane‐type siloxane–polyhedral oligomeric silsesquioxane [(HSiO~3/2~)~8~, T~8~^H^] copolymers were synthesized by the dehydrogenative condensation of T~8~^H^ with diphenylsilanediol, tetraphenyldisiloxane‐1,3‐diol or silanol‐terminated polydimethylsiloxanes in the presence of die