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Polyhedral liquid crystal silsesquioxanes

✍ Scribed by Georg H. Mehl; Isabel M. Saez

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
151 KB
Volume
13
Category
Article
ISSN
0268-2605

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✦ Synopsis

Synthetic routes towards monodisperse polyhedral liquid-crystalline silsesquioxanes are described. The liquid-crystalline phase behaviour of these structurally uniform materials, with various silsesquioxane core and mesogenic side-chain structures, were analysed and compared with those of related oligomeric and polymeric materials. Common features of the solid-state behaviour of these organic/inorganic hybrids, which form self-organized structures in their soft-matter states, were identified. Copyright

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