Poly(ethy1ene terephthalate) copolymers were prepared by melt polycondensation of dimethyl terephthalate and excess ethylene glycol with 10- 40 mol% (in feed) of poly(ethy1ene glycol) (E) and poly(tetramethy1ene glycol) (B), with molecular weight (MW) of E and B 200-7500 and 1000, respectively. The
Poly(ester–carbonates) containing poly(lactic–glycolic acid) and poly(ethylene glycol) segments
✍ Scribed by Maurizio Penco; Michele Becattini; Paolo Ferruti; Salvatore D'antone; Ramano Deghenghi
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 486 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1042-7147
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✦ Synopsis
The aim of the present paper is to report on the synthesis, characterization and structure-property relationships of a novel family of highly hydrophilic segmented copoly (esterether-carbonafes). The synthetic process is based on a chain-extension reaction involving low molecular weight poly(1actic-glycolic acid) copolymers, obtained by thermal polycondensation, and the a, wbis(ch1oroformates) of poly(ethy1ene glycol)s. The resulting products have been characterized in terms of molecular weight, thermal properties and water absorption. KEYWORDS: poo(lactic-fycolic acid); block copolymers; bi egradab e polymers; poly(estercarbonates); poly(ethy1ene g ycol)
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