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Poly[[diaqua­samarium(III)]-μ3-(biphenyl-4,4′-dicarboxyl­ato)-μ3-(4′-carboxyl­biphenyl-4-carboxyl­ato)]

✍ Scribed by Yu, Bin ;Wang, Xiao-Qing ;Kou, Hui-Zhong ;Shen, Guang-Qiu ;Shen, De-Zhong

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
96 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

Poly [[diaquasamarium(III)]-l 3 -(biphenyl-4,4 0 0 0 -dicarboxylato)-l 3 -(4 0 0 0 -carboxylbiphenyl-4-carboxylato)]

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Single-crystal X-ray study T = 293 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.025 wR factor = 0.062 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Poly[diaqua-μ4-benzene-1,4-dicarboxyl­at
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✍ Zhang, Wen-Zhi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 284 KB

In the title compound, [Gd~2~(C~8~H~4~O~4~)~3~(C~3~H~7~NO)~2~(H~2~O)~2~]~__n__~, the central Gd^III^ atom is nine-coordinated by seven O atoms from benzene-1,4-dicarboxylate (1,4-BDC) ligands, one dimethylformamide and one water molecule in a distorted tricapped trigonal–prism coordination. The 1,4-