Poly[diaquabis(μ2-4,4′-bipyridine)bis(μ3-5,5′-dicarboxybiphenyl-2,2′-dicarboxylato)dicobalt(II) tetrahydrate]
✍ Scribed by Xu, Ji-Yang ;Contreras, Damacio S. ;Fronczek, Frank R. ;Chen, Banglin
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 463 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Poly[diaquabis(l 2 -4,4 0 0 0 -bipyridine)bis(l 3 -5,5 0 0 0dicarboxybiphenyl-2,2 0 0 0 -dicarboxylato)dicobalt(II) tetrahydrate]
📜 SIMILAR VOLUMES
l-Benzene-1,2,4,5-tetracarboxylato-bis-[aquabis(2,2 0 0 0 -bipyridine)cobalt(II)] dodecahydrate
The title complex, (C 3 H 5 N 2 ) 2 [Co(C 7 H 3 NO 4 ) 2 (H 2 O) 2 ]Á4H 2 O, was prepared by a hydrothermal reaction. Each Co II atom is located on a crystallographic inversion centre and displays a distorted octahedral coordination geometry. The face-to-face distance of 3.529 (7) A ˚between partial
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.023 wR factor = 0.091 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Poly[bis(4,4 0 0 0 -bipyridine)(l 3 -4,4 0 0 0 -dicarboxybiphenyl-3,3 0 0 0 -dicarboxylato)cobalt(II)]
In the title compound, [Gd~2~(C~8~H~4~O~4~)~3~(C~3~H~7~NO)~2~(H~2~O)~2~]~__n__~, the central Gd^III^ atom is nine-coordinated by seven O atoms from benzene-1,4-dicarboxylate (1,4-BDC) ligands, one dimethylformamide and one water molecule in a distorted tricapped trigonal–prism coordination. The 1,4-