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Polydentate N 2 S 2 O and N 2 S 2 O 2 Ligands as Alcoholic Derivatives of ( N , N ‘-Bis(2-mercaptoethyl)-1,5-diazacyclooctane)nickel(II) and ( N , N ‘-Bis(2-mercapto-2-methylpropane)-1,5-diazacyclooctane)nickel(II)

✍ Scribed by Goodman, Dawn C.; Buonomo, Rizalia M.; Farmer, Patrick J.; Reibenspies, Joseph H.; Darensbourg, Marcetta Y.


Book ID
126398114
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
419 KB
Volume
35
Category
Article
ISSN
0020-1669

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In mononuclear [Ni(C 8 H 11 N 2 O 3 S) 2 ], a nickel(II) complex of 2-(2-pyridylmethylamino)ethanesulfonic acid, the six-coordinate Ni atom lies on a centre of symmetry. The monodeprotonated anion coordinates in a facial arrangement through two N and one O atoms. Intermolecular N-HÁ Á ÁO hydrogen bo