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Applications of the N2S2 ligand, N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane (BME-DACO), toward the formation of bi- and heterometallics: [(BME-DACO)Fe]2 and [(BME-DACO)NiFeCl2]2

✍ Scribed by Mills, Daniel K.; Hsiao, Yui May; Farmer, Patrick J.; Atnip, Earl V.; Reibenspies, Joseph H.; Darensbourg, Marcetta Y.


Book ID
126182812
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
442 KB
Volume
113
Category
Article
ISSN
0002-7863

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Iron Complexes Containing the Ligand N,N
✍ Véronique Balland; Frédéric Banse; Elodie Anxolabéhère-Mallart; Martine Nierlich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB

## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole