𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Poly[[chloro­manganese(II)]-μ4-imidazole-1,3-diyldiacetato]

✍ Scribed by Zhang, Xian-Fa ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
177 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title coordination polymer, [Mn(C 7 H 7 N 2 O 4 )Cl] n , each Mn 2+ ion has a distorted octahedral geometry, defined by four acetate O atoms from four different imidazolyl-1,3-diyldiacetate (IDA À ) ligands and two Cl À ions. The IDA À groups serve as bridging ligands to link the Mn 2+ ions into a twodimensional layer structure.

📜 SIMILAR VOLUMES

Poly[aqua­manganese(II)-μ3-1H-imidazole-
Poly[aqua­manganese(II)-μ3-1H-imidazole-4,5-dicarboxyl­ato]
✍ Gao, Shan ;Huo, Li-Hua ;Zhao, Hui ;Liu, Ji-Wei 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 231 KB

In the title coordination polymer, [Mn(HIDC)(H 2 O)] n (HIDC 2À is the 1H-imidazole-4,5-dicarboxylate dianion, C 5 H 2 N 2 O 4 ), each Mn II atom is in an octahedral coordination by one N atom and four carboxylate O atoms from three HIDC 2À anions, and one water molecule. The Mn II atoms are linked

Poly[bis­(μ2-1H-imidazolyl-1,3-diyldiace
Poly[bis­(μ2-1H-imidazolyl-1,3-diyldiacetato-κ4O,O′:O′′′,O′′′')cadmium(II)]
✍ Zhang, Xian-Fa ;Gao, Shan ;Huo, Li-Hua ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 287 KB

zwitterions link Cd 2+ cations into a network of [Cd(C 7 H 7 N 2 O 4 ) 2 ] n sheets. The carboxylate arms of the ligand chelate to the metal, which shows square-antiprismatic coordination. The Cd 2+ ion occupies a special position 2 site symmetry. The crystals were found to be twinned. metal-organic