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Poly[bis(μ2-1H-imidazolyl-1,3-diyldiacetato-κ4O,O′:O′′′,O′′′')cadmium(II)]

✍ Scribed by Zhang, Xian-Fa ;Gao, Shan ;Huo, Li-Hua ;Ng, Seik Weng

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 287 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806041407

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✦ Synopsis

zwitterions link Cd 2+ cations into a network of [Cd(C 7 H 7 N 2 O 4 ) 2 ] n sheets. The carboxylate arms of the ligand chelate to the metal, which shows square-antiprismatic coordination. The Cd 2+ ion occupies a special position 2 site symmetry. The crystals were found to be twinned. metal-organic papers m2912 Zhang et al. [Cd(C 7 H 7 N 2 O 4 ) 2 ]

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✦ Synopsis

Poly[bis(μ2-1H-imidazolyl-1,3-diyldiacetato-κ4O,O′:O′′′,O′′′')cadmium(II)]