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Poly[bis(μ2-O,O′-dimethyl dithiophosphato)mercury(II)]

✍ Scribed by Ito, Tetsuzo

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 87 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806023658

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✦ Synopsis

In the title compound, [Hg(C~2~H~6~O~2~PS~2~)~2~]~n~, the Hg atom is coordinated by four S atoms in a distorted tetrahedral arrangement. The Hg—S bond distances are in the range 2.508 (2)–2.662 (2) Å, and the six S—Hg—S angles are in the range 99.14 (7)–118.77 (8)°. In the crystal structure, a two-dimensional network of 16-membered rings of [–Hg–S–P–S–]~4~ is formed parallel to the (100) plane.

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Poly[bis­(μ2-O,O′-dimethyl dithio­phosphato)mercury(II)]

✦ Synopsis

Poly[bis(μ2-O,O′-dimethyl dithiophosphato)mercury(II)]