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Poly[[bis{μ2-N2,N6-bis[(pyridin-3-yl)methyl]pyridine-2,6-dicarboxamide}dichloridonickel(II)] N,N-dimethylformamide tetrasolvate]

✍ Scribed by Guo, Yi-Ping ;Li, Dong-Ying ;Li, Guo-Ting

Book ID: 117856203
Publisher: International Union of Crystallography
Year: 2012
Tongue: English
Weight: 764 KB
Volume: 68
Category: Article
ISSN: 0108-2701
DOI: 10.1107/s010827011203750x

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Treatment of deprotonated N,N 0 -bis-(4-methyl-2-benzothiazolyl)-2,6-pyridicarboxamide (L 2À ) with CuCl 2 Á2H 2 O yields the mononuclear title complex, CuL(H 2 O) or [Cu(C 23 H 15 N 5 -O 2 S 2 )(H 2 O)]. The Cu II atom adopts a distorted square-planar coordination geometry, binding to two deprotona