Polarographic reduction of benzoylacetanilides, mechanism and structure-reactivity relationships
✍ Scribed by A. Sami Shawali; B.E. Alanadouli; M.H. Sammour
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 620 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0013-4686
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~Theelectroreduction ofa series of 3-phenyl-2Jdioxopropionanilide 2-arylhydrazones (III) on the dropping mercury electrode (dme) was investigated in eihanolic B&ton-Robinson buffers. In each case, the polarographic curves showed two waves, A and B, corresponding to a four-and a two-electron process,
AMract -The polarographic reduction of cresol red, thymol blue, bromocresol purple, bromophenol blue and bromocresol green are studied in buffered aqueous solutions and alcohol-water mixtures of pH 2-11.5. It w'aa found that in solutions of pH values Z 10 the five depolarizers are reduced along two
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## Abstract Absolute rate constants (__k__~eff~) for the chemical reactions of Cu(II)~2~(3,5‐di‐__iso__‐propylsalicylate)~4~(H~2~O)~3~, Cu(II)~2~(3,5‐di‐__tert__‐butylsalicylate)~4~, Cu(II)~2~(3,5‐di‐__tert__‐butylsalicylate)~4~(H~2~O)~4~, Cu(II)~2~(3,5‐dimethylsalicylate)~4~(H~2~O)~3~, Cu(II)~2~(3