Electrochemical reduction of bromonitriles: mechanism and polarographic maxima
β Scribed by Antonella Curulli; Italo Carelli; AChille Inesi
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 893 KB
- Volume
- 235
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
~Theelectroreduction ofa series of 3-phenyl-2Jdioxopropionanilide 2-arylhydrazones (III) on the dropping mercury electrode (dme) was investigated in eihanolic B&ton-Robinson buffers. In each case, the polarographic curves showed two waves, A and B, corresponding to a four-and a two-electron process,
The reduction potentials, Ells, of ethyl cinnamate, ethyl crotonate, triphenylcyanopropylphosphonium bromide and cycle-octatetraene have been determined polarographically in dimethylfor-man-ride solvent as a function of the size of the tetra-n-alkylammonium cation used as a supporting electrolyte.