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Polar substituent effects in the solvolysis of 2-methyl-2-exo-norbornyl 2,4-dinitrophenyl ethers

✍ Scribed by C.A. Grob; A. Waldner


Book ID
108381896
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
176 KB
Volume
21
Category
Article
ISSN
0040-4039

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The solvolysis rates and products of the tertiary 2-methyl-2-exo-and -2-endonorbornyl 2,4-dinitrophenyl ethers 1 and 2, (X = 2,4-(NO,),C,H,O) have been determined. The different sensitivities of the rates of these ethers to the inductive effect of substituents at C(6) indicate that graded bridging o

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The effect of substituents at C4, 5, 6 and 7 on solvolysis rates and products of 2-exo-and 2-endo-norbornyl tosylates confirms that differential carbon participation is responsible for varying exo/endo rate and product ratios.