Polar substituent effects in the solvolysis of 2-methyl-2-endo-norbonyl 2,4-dinitrophenyl ethers
β Scribed by C.A. Grob; A. Waldner
- Book ID
- 104225169
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 153 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
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Hydrolysisofbicyclo[2.2.2]octylp-nitrobenzenesulfonate (14a,X =p-N02C6H4S03), and nineteen 4-R-substituted derivatives 14b-14 t in 70% aqueous dioxane yield the corresponding bicyclo [2.2.2]octanols 14 (X = OH), exclusively. The 7-center fragmentation to 1,4-dimethylidene-cyclohexane (15) is not obs
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