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Polar substituent effects in the solvolysis of 2-methyl-2-endo-norbonyl 2,4-dinitrophenyl ethers

✍ Scribed by C.A. Grob; A. Waldner


Book ID
104225169
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
153 KB
Volume
21
Category
Article
ISSN
0040-4039

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## Abstract The solvolysis rates and products of the 6__endo__‐R‐substituted 2__endo__‐norbornyl toluenesulfonates **6a**–**6i** have been determined. The rates of **6a**–**6g** correlate with the inductive constants Οƒ the 6__endo__‐substituents and are not related to the size of the latter. It is