Polar effects in radical reactions. II. Nucleophilic character of the undecyl radical
✍ Scribed by Henderson, Richard W.; Ward, R. D.
- Book ID
- 126110455
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 291 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Rate constants (k) of radical addition reactions between 15 carbon-and sulfur-centered radicals and 15 vinyl-type alkenes were collected from the literature. Three descriptor variables {a polar (Hammett) sigma scale [s(H)] and two radical sigma scales as defined by Creary and co-workers [s Á (C)] an
## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi