𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polar effects in radical reactions. IV. Nucleophilic character of the 3-heptyl radical

✍ Scribed by Henderson, Richard W.

Book ID
126257682
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
390 KB
Volume
97
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Separation of polar and enthalpy effects
Separation of polar and enthalpy effects in radical addition reactions using polar (Οƒ) and radical (Οƒ Β·) sigma scales
✍ KΓ‘roly HΓ©berger; Antal Lopata; J. Cs. JΓ‘szberΓ©nyi πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 87 KB πŸ‘ 2 views

Rate constants (k) of radical addition reactions between 15 carbon-and sulfur-centered radicals and 15 vinyl-type alkenes were collected from the literature. Three descriptor variables {a polar (Hammett) sigma scale [s(H)] and two radical sigma scales as defined by Creary and co-workers [s Á (C)] an