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Polar effects in radical reactions. II. Positive .rho. for the reaction of tert-butyl radicals with substituted toluenes

✍ Scribed by Pryor, William A.; Davis, William H.; Stanley, J. P.

Book ID
126120375
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
427 KB
Volume
95
Category
Article
ISSN
0002-7863

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Nucleophilic character of the tert-butyl
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## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi

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