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P*,N-Bidentate Amino Phosphoramidites: New Highly Effective Ligands for Pd-Catalyzed Asymmetric Allylic Substitution.

✍ Scribed by Konstantin N. Gavrilov; Vasily N. Tsarev; Alexei A. Shiryaev; Oleg G. Bondarev; Sergey E. Lyubimov; Eduard B. Benetsky; Alexander A. Korlyukov; Mikhail Yu. Antipin; Vadim A. Davankov; Hans-Joachim Gais


Publisher
John Wiley and Sons
Year
2004
Weight
144 KB
Volume
35
Category
Article
ISSN
0931-7597

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P*,N-Bidentate Amino Phosphoramidites: N
✍ Konstantin N. Gavrilov; Vasily N. Tsarev; Alexei A. Shiryaev; Oleg G. Bondarev; 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB

## Abstract New chiral __P\*__,__N__‐hybrid amino phosphoramidites have been obtained by one‐step phosphorylation of amino alcohols. Complexation of the new ligands with [Rh(CO)~2~Cl]~2~ and [Pd(allyl)Cl]~2~ gave the corresponding chelate complexes [Rh(CO)Cl(η^2^‐P,N)] and [Pd(allyl)(η^2^‐P,N)]^+^B