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P(MeNCH 2 CH 2 ) 3 N: An Efficient Promoter for the Reduction of Aldehydes and Ketones with Poly(methylhydrosiloxane)

โœ Scribed by Wang, Zhigang; Wroblewski, Andrzej E.; Verkade, John G.


Book ID
126053942
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
40 KB
Volume
64
Category
Article
ISSN
0022-3263

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P(MeNCH2CH2CH2)3N: An efficient promoter
โœ Xiang-Shu Fei; John G. Verkade ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 114 KB ๐Ÿ‘ 2 views

The commercially available nonionic strong base P(MeNCH 2 CH 2 ) 3 N promotes the formation of stable and nonstable sulfur ylides from sulfonium salts at room temperature without competing [2,3] sigmatropic rearrangement. The ylides generated in situ reacted with aldehydes to give the corresponding