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ChemInform Abstract: P(MeNCH2CH2)3N: An Efficient Promoter for the Reduction of Aldehydes and Ketones with Poly(methylhydrosiloxane).

✍ Scribed by Zhigang Wang; Andrzej E. Wroblewski; John G. Verkade

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200007068

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The commercially available nonionic strong base P(MeNCH 2 CH 2 ) 3 N promotes the formation of stable and nonstable sulfur ylides from sulfonium salts at room temperature without competing [2,3] sigmatropic rearrangement. The ylides generated in situ reacted with aldehydes to give the corresponding

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P(MeNCH 2 CH 2 ) 3 N: An Efficient Nonionic Superbase for Wittig and Wittig-Horner Reactions. -The strong non-ionic title base effectively deprotonates triphenylphosphonium salts (I) and phosphonates (IV) under mild conditions. Reaction of the ylides generated with aldehydes provides an efficient a

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ChemInform Abstract: P(MeNCH2CH2)3N: An Efficient Promoter for the Generation of Nonstable and Somewhat Stable Sulfur Ylides from Sulfonium Salts.

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