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ChemInform Abstract: P(MeNCH2CH2)3N: An Efficient Promoter for the Generation of Nonstable and Somewhat Stable Sulfur Ylides from Sulfonium Salts.

โœ Scribed by Xiang-Shu Fei; John G. Verkade


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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P(MeNCH2CH2CH2)3N: An efficient promoter
โœ Xiang-Shu Fei; John G. Verkade ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 114 KB ๐Ÿ‘ 2 views

The commercially available nonionic strong base P(MeNCH 2 CH 2 ) 3 N promotes the formation of stable and nonstable sulfur ylides from sulfonium salts at room temperature without competing [2,3] sigmatropic rearrangement. The ylides generated in situ reacted with aldehydes to give the corresponding