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Platinum-catalyzed dehydrogenative double silylation of carbonyl compounds with o-bis(dimethylsilyl)benzene

✍ Scribed by Uchimaru, Yuko; Lautenschlager, Hans Juergen; Wynd, Andrew J.; Tanaka, Masato; Goto, Midori

Book ID
126077175
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
541 KB
Volume
11
Category
Article
ISSN
0276-7333

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Nickel-Catalyzed Double Silylation of a
Nickel-Catalyzed Double Silylation of a Variety of Carbonyl Compounds with 1,2-Bis(dimethylsilyl)carborane
✍ Kang, Youngjin; Kim, Jinsik; Kong, Young Kun; Lee, Jihwa; Lee, Soon W.; Kang, Sa πŸ“‚ Article πŸ“… 2000 πŸ› American Chemical Society 🌐 English βš– 108 KB

The nickel-catalyzed reactions of 1,2-bis(dimethylsilyl)carborane 1 with aldehydes such as isobutyraldehyde, trimethylacetaldehyde, hexanal, and benzaldehyde afforded 5,6carboranylene-2-oxa-1,4-disilacyclohexanes. The dehydrogenative 1,4-double silylation of methacrolein and trans-4-phenyl-3-buten-2