Nickel-Catalyzed Double Silylation of a
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Kang, Youngjin; Kim, Jinsik; Kong, Young Kun; Lee, Jihwa; Lee, Soon W.; Kang, Sa
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Article
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2000
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American Chemical Society
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English
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The nickel-catalyzed reactions of 1,2-bis(dimethylsilyl)carborane 1 with aldehydes such as isobutyraldehyde, trimethylacetaldehyde, hexanal, and benzaldehyde afforded 5,6carboranylene-2-oxa-1,4-disilacyclohexanes. The dehydrogenative 1,4-double silylation of methacrolein and trans-4-phenyl-3-buten-2