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Nickel-Catalyzed Double Silylation of a Variety of Carbonyl Compounds with 1,2-Bis(dimethylsilyl)carborane

โœ Scribed by Kang, Youngjin; Kim, Jinsik; Kong, Young Kun; Lee, Jihwa; Lee, Soon W.; Kang, Sang Ook; Ko, Jaejung


Book ID
118210956
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
108 KB
Volume
19
Category
Article
ISSN
0276-7333

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Nickel-Catalyzed Double Silylation of a
โœ Kang, Youngjin; Kim, Jinsik; Kong, Young Kun; Lee, Jihwa; Lee, Soon W.; Kang, Sa ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 108 KB

The nickel-catalyzed reactions of 1,2-bis(dimethylsilyl)carborane 1 with aldehydes such as isobutyraldehyde, trimethylacetaldehyde, hexanal, and benzaldehyde afforded 5,6carboranylene-2-oxa-1,4-disilacyclohexanes. The dehydrogenative 1,4-double silylation of methacrolein and trans-4-phenyl-3-buten-2