𝔖 Bobbio Scriptorium
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Plasma reaction of group VI metal carbonyls

✍ Scribed by H. Suhr; R. Schmid; W. Stürmer


Book ID
105201749
Publisher
Springer
Year
1992
Tongue
English
Weight
499 KB
Volume
12
Category
Article
ISSN
0272-4324

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📜 SIMILAR VOLUMES


Octahedral metal carbonyls. : XXXVII. th
✍ J.E. Pardue; G.R. Dobson 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo