Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo
✦ LIBER ✦
Photoinduced metathesis and other reactions of olefins by group VI metal carbonyls
✍ Scribed by T. Szymańska-Buzar
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 888 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0304-5102
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