𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Octahedral metal carbonyls. XVII (1). Group VI-B metal carbonyl complexes of ethylenediphosphine

✍ Scribed by Gerard R. Dobson; Albert J. Rettenmaier

Book ID
107768516
Publisher
Elsevier Science
Year
1970
Weight
185 KB
Volume
6
Category
Article
ISSN
0020-1650

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Octahedral metal carbonyls. : XXXVII. th
Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls
✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo