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Planar chiral ferrocenes as ligands in the vanadium-catalyzed asymmetric epoxidation of allylic alcohols

✍ Scribed by Carsten Bolm; Toralf Kühn


Book ID
119922810
Publisher
Laser Pages Publishing Ltd.
Year
2001
Tongue
English
Weight
66 KB
Volume
41
Category
Article
ISSN
0021-2148

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Asymmetric epoxidation of allylic alcoho
✍ Hsyueh-Liang Wu; Biing-Jiun Uang 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 256 KB

Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.

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