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Planar Chiral Cyclic Ether: Asymmetric Resolution and Chirality Transformation

โœ Scribed by Tomooka, Katsuhiko; Komine, Nobuyuki; Fujiki, Daisuke; Nakai, Takeshi; Yanagitsuru, Syun-ichi


Book ID
126062105
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
94 KB
Volume
127
Category
Article
ISSN
0002-7863

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Stereocontrol of cyclophane-type planar chirality was investigated via adsorption-induced asymmetric transformation (AIAT) on a series of inorganic porous adsorbents. The rope-skipping equilibria between bridged nicotinamides (S,3%S)-1 and (R,3%S)-2 shifted preferentially to (R,3%S)-2 to accumulate