Adsorption-induced asymmetric transforma
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Nobuhiro Kanomata; Jun Oikawa
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Article
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2003
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Elsevier Science
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French
โ 148 KB
Stereocontrol of cyclophane-type planar chirality was investigated via adsorption-induced asymmetric transformation (AIAT) on a series of inorganic porous adsorbents. The rope-skipping equilibria between bridged nicotinamides (S,3%S)-1 and (R,3%S)-2 shifted preferentially to (R,3%S)-2 to accumulate