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Stereocontrol of molecular jump-rope: crystallization-induced asymmetric transformation of planar-chiral cyclophanes

โœ Scribed by Nobuhiro Kanomata; Yoshiharu Ochiai


Book ID
104211587
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
96 KB
Volume
42
Category
Article
ISSN
0040-4039

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Adsorption-induced asymmetric transforma
โœ Nobuhiro Kanomata; Jun Oikawa ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 148 KB

Stereocontrol of cyclophane-type planar chirality was investigated via adsorption-induced asymmetric transformation (AIAT) on a series of inorganic porous adsorbents. The rope-skipping equilibria between bridged nicotinamides (S,3%S)-1 and (R,3%S)-2 shifted preferentially to (R,3%S)-2 to accumulate