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Synchronized stereocontrol of planar chirality by crystallization-induced asymmetric transformation

โœ Scribed by Nobuhiro Kanomata; Gou Mishima; Jun Onozato

Book ID
104096013
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
234 KB
Volume
50
Category
Article
ISSN
0040-4039

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Stereocontrol of cyclophane-type planar chirality was investigated via adsorption-induced asymmetric transformation (AIAT) on a series of inorganic porous adsorbents. The rope-skipping equilibria between bridged nicotinamides (S,3%S)-1 and (R,3%S)-2 shifted preferentially to (R,3%S)-2 to accumulate