Pincer and Diamine Ru and Os Diphosphane Complexes as Efficient Catalysts for the Dehydrogenation of Alcohols to Ketones
β Scribed by Prof. Walter Baratta; Dr. Gianluca Bossi; Dr. Elisabetta Putignano; Prof. Pierluigi Rigo
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 293 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
2,2Π-Bipyridines / C 2 -symmetric diamines / Sodium phosphonate / Water-soluble catalyst / Hydrogenation New water-soluble rhodium and iridium complexes of 2,2Π-substituted acetophenones under hydrogen pressure in basic aqueous media. No significant loss of catalyst activity is bipyridines, function
## Abstract Complexes prepared __in__ situ from RuCl~2~(PPh~3~)~3~ and chiral phosphineβoxazoline ligands are effective catalysts for the hydrogenation of various aryl ketones with ees up to 99% and substrate to catalyst ratios of 10,000β50,000; the reaction tolerates high substrate concentrations