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Picosecond studies of vibrational energy decay in the condensed phase

✍ Scribed by J.B. Hopkins; P.M. Rentzepis

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 420 KB
Volume: 117
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80274-8

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✦ Synopsis

Lime-resolved emission OC single vlbrarional level lluorescen~ from large matrix-isolated molecules has been observed for the firs1 IIme. Using the strucrured emrssion speclra rrom S, azulenc we have studred tie demiled pathways and dynamics of vibrarional energy relaxalion. TemperaLure and man-~x media erlects are used LO elucidate the detailed couphng mechanrsm which promotes energy exchange between the molecule and iare-gas media.

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