✦ LIBER ✦
Time-resolved multiphoton ionization in the organic condensed phase: Picosecond conformational dynamics of cis-stilbene and tetraphenylethylene
✍ Scribed by B.I. Greene; T.W. Scott
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 372 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Picosecond time-resolved mulnphoton ionization has brcn esrcnded IO studies of photochemical d) rumics m the condenscd phase. The early time dynamics of phenyl-substituted ethylenes reflect the loss of S, -'3,~ rcson~ntly snhan'rd ionization due to conformational motion along the isomcrization coordinate. Rlcasurcd Ilfalmrs of 5.7 f 0.1 ps 2nd I.2 I 0.2 ps arc rhcrcby obtained for tctraphcnylcthylcnc and cis-stilbcne, respectively. in n-hcxanc valurion.