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Picosecond photodissociation of tetraphenylhydrazine

โœ Scribed by Martin G. Hyde; Gavin D. Reid; Godfrey S. Beddard

Book ID
103033634
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
408 KB
Volume
190
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES

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Photodissociation of tetraphenylhydrazine produces two diphenylaminyl radicals within I ps. A transient anisotropy, due to the diphenylaminyl radicals, has been measured and is described by a model based on the rotational diffusion of two initially correlated ellipsoids. A tetrahedral geometry for t

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The primary photodissociation of dibenzyl ketone (DBK) to form the benzyl radical is examined by picosecond transient absorption (PTA) spectroscopy. This initial process precedes decarbonylation of the phenacetyl radical. Dissociation is initiated at 282 nm in solutions of methanol and cyclohexane a