Transient Raman spectra of anisole cation (C6HJOCH$') and its para methyl derivative are reported. These radicals were prepared on the 100 ns time scale by electron transfer reactions in aqueous solution. The structural contents in these Raman spectra are much more extensive than in the recently stu
Picosecond kinetics and transient spectra of pseudoisocyanine monomers and J-aggregates in aqueous solution
β Scribed by S.K. Rentsch; R.V. Danielius; R.A. Gadonas; A. Piskarskas
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 371 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Free radicals are generated in liquid solutions by harmonically modulated photolysis of suitable substrates. Harmonic analysis of the absorbance as functions of wavelength and modulation frequency yields the optical spectra and the decay kinetics of the transient species. The experiment
The degradation kinetics and mechanism of a potent new cephalosporin, cefotaxime sodium, in aqueous solution were investigated at pH 0-10 at 25 degrees and an ionic strength of 0.5. The degradation rates were determined by high-pressure liquid chromatography and were observed to follow pseudo first-
The decomposition reactions of N-bromodiethanolamine. N-bromoethylethanolamine, and AT-bromomethylethanolamine in aqueous solution have been studied kineticall) under various experimental conditions. The results support a proposed reaction mechanism in which the rate controlling step is assumed to b