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Physicochemical study of polymer-stabilized platinum catalysts for enantioselective hydrogenation of ketones

✍ Scribed by A. V. Bykov, M. B. Konyaeva, G. N. Demidenko, V. G. Matveeva…

Book ID
120670183
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
496 KB
Volume
4
Category
Article
ISSN
2070-0504

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Enantioselective hydrogenation of pyruva
Enantioselective hydrogenation of pyruvates over polymer-stabilized and supported platinum nanoclusters
✍ Xiaobin Zuo; Hanfan Liu; Dawei Guo; Xiaozhen Yang 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 828 KB

The cinchonidine-modified enantioselective hydrogenation of pyruvates has been studied over polyvinylpyrrolidone-stabilized platinum (PVP-Pt) and the corresponding alumina-supported platinum (AI203-Pt) clusters. It is shown that the catalysts with particle size less than 2.0 um demonstrate >90% enan