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Highly efficient new catalysts for enantioselective transfer hydrogenation of ketones

✍ Scribed by Thomas Langer; Günter Helmchen


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
264 KB
Volume
37
Category
Article
ISSN
0040-4039

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✍ Du Xiang-Dong; Dai Li-Xin; Hou Xue-Long; Xia Li-Jun; Tang Ming-Hua 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB 👁 1 views

Planar chiral ferrocenes 1 and its diastereoisomer 2 were found to be good ligands for. the ruthenium catalyzed asymmetric transfer hydrogenation of ketones with i-PrOH as hydrogen source under refluxing in the presence of sodium hydroxide. The results showed that the absolute configuration of alcoh