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Enantioselective hydrogenation of trifluoroacetophenone over polymer-stabilized platinum nanoclusters

✍ Scribed by Jie Zhang; XiaoPing Yan; HanFan Liu

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
90 KB
Volume
175
Category
Article
ISSN
1381-1169

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Enantioselective hydrogenation of pyruva
Enantioselective hydrogenation of pyruvates over polymer-stabilized and supported platinum nanoclusters
✍ Xiaobin Zuo; Hanfan Liu; Dawei Guo; Xiaozhen Yang πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 828 KB

The cinchonidine-modified enantioselective hydrogenation of pyruvates has been studied over polyvinylpyrrolidone-stabilized platinum (PVP-Pt) and the corresponding alumina-supported platinum (AI203-Pt) clusters. It is shown that the catalysts with particle size less than 2.0 um demonstrate >90% enan