Photostability, Electrochemistry, and Monolayers of [M(bpy) 2 ( trans -1,2-bis(4-pyridyl)ethylene)L] + (M = Ru, Os; L = Cl, H 2 O)
โ Scribed by Forster, Robert J.; Figgemeier, Egbert; Lees, Anthea C.; Hjelm, Johan; Vos, Johannes G.
- Book ID
- 126146563
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 51 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0743-7463
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๐ SIMILAR VOLUMES
## Abstract The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surfaceโassisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixedโmetal compounds.
Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a