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Synthesis and redox properties of trans-[MBr2(L)4] (M = Ru, Os, L = PPhH2, PPh2H; M = Os, L = PCy2H) and the crystal structure of trans-[OsBr2 (PPh2H)4]Et2O

✍ Scribed by Robin J. Forder; Gillian Reid


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
475 KB
Volume
15
Category
Article
ISSN
0277-5387

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## Abstract The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surface‐assisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixed‐metal compounds.