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Surface-Assisted Synthesis and Behavior of Dimetallic Mixed-Metal Complexes [M2Cl2(μ-Cl)4(CO)6M′(L)2] (M = Ru, Os; M′ = Fe, Co; L = CH3CH2OH, H2O)

✍ Scribed by Minna Jakonen; Pipsa Hirva; Taina Nivajärvi; Mirja Kallinen; Matti Haukka

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
43 KB
Volume
2008
Category
Article
ISSN
1434-1948

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Surface-Assisted Synthesis and Behavior
Surface-Assisted Synthesis and Behavior of Dimetallic Mixed-Metal Complexes [M2Cl2(μ-Cl)4(CO)6M′(L)2] (M = Ru, Os; M′ = Fe, Co; L = CH3CH2OH, H2O)
✍ Minna Jakonen; Pipsa Hirva; Taina Nivajärvi; Mirja Kallinen; Matti Haukka 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 275 KB

## Abstract The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surface‐assisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixed‐metal compounds.

Asymmetric Heterodinuclear [L′Ru(μ-O)(μ-
Asymmetric Heterodinuclear [L′Ru(μ-O)(μ-CH3CO2)2ML]2⊕ Complexes (M Fe, Mn, V): Electronic Structure and Magnetic Properties
✍ Dipl.-Chem. Rainer Hotzelmann; Prof. Dr. Karl Wieghardt; Dr. Ulrich Flörke; Prof 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 364 KB 👁 1 views

I l l The Ir-bond orders calculated from the bond lengths according to established equations"2] are 1.00 for the C5-C6 bond. 0.34 for the C5--N3 bond, and 0.15 for the C&N4 bond. [12] G .

Heterometallic analogues of [{M(CO)2(η-C
Heterometallic analogues of [{M(CO)2(η-C5H5)}2] (M = Fe, Ru, Os). The synthesis of the tetracarbonylcyclopentadienylcycloheptatrienyl complexes [M(CO)2(η-C5H5)M′(CO)2(η-C7H7)] (M = Fe, Ru; M′ = Mo, W). Crystal structures of [Ru(CO)2(η-C5H5Mo(CO)2(η-C7H7)] (RuMo) and [Mo(CO)3(μ-η6, η1-C7H7)Ru(CO)2(η-C5Me5)]
✍ Roy L. Beddoes; E.Stephen Davies; Madeleine Helliwell; Mark W. Whiteley 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 1014 KB