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Photosensitized electron transfer oxidation of 2-substituted 1,3-dithiolane to 1,3-dithiolane-1-oxide

โœ Scribed by Bipin Pandey; Smita Y. Bal; Uday R. Khire

Book ID
104229461
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
162 KB
Volume
30
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Irradiation of a solution of 1,3-dithiolane, I-cyanonaphthalene in 02-saturated CH3CN:H20 350 nm furnishes good yields of 1,3-dithiolane-l-oxide.

1,3-Dithiolanes constitute an important functional group in organic chemistry. However, its photochemistry remains underexplored. Eaton et al. 2 observed that the photolysis of 1,3-dithiolanes, in the absence of oxygen, led to product(s) by initial C-S bond cleavage, whereas Takahasi et al. 3 reported a unique photo-dethioketalization of various 1,3-dithiolanes in the presence of triplet sensitizers and molecular oxygen. Foote et al. the H-NMR, IR, GC, TLC of authentic samples. 11. P.S. Mariano in "Synthetic Organic Photochemistry",

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