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ChemInform Abstract: Carbonyl Regeneration by Oxidative Cleavage of 1,3-Dithiolanes and 1,3- Dithianes.

โœ Scribed by P. CECCHERELLI; M. CURINI; M. C. MARCOTULLIO; F. EPIFANO; O. ROSATI


Book ID
112040992
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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A convenient oxidative demasking of 1,3-
โœ Nivrutti B Barhate; Popat D Shinde; Vishal A Mahajan; Radhika D Wakharkar ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 91 KB

Regeneration of carbonyl compounds from their 1,3-dithiolanes and dithianes was achieved using tert-butyl hydroperoxide (TBHP, aq. 70%) in high yields. Thus, an efficient, economic and experimentally simple protocol for dethioacetalization has been demonstrated.