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A convenient oxidative demasking of 1,3-dithiolanes and dithianes to carbonyl compounds with TBHP

✍ Scribed by Nivrutti B Barhate; Popat D Shinde; Vishal A Mahajan; Radhika D Wakharkar

Book ID: 104251602
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 91 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)01210-8

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✦ Synopsis

Regeneration of carbonyl compounds from their 1,3-dithiolanes and dithianes was achieved using tert-butyl hydroperoxide (TBHP, aq. 70%) in high yields. Thus, an efficient, economic and experimentally simple protocol for dethioacetalization has been demonstrated.

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