Regeneration of carbonyl compounds from their 1,3-dithiolanes and dithianes was achieved using tert-butyl hydroperoxide (TBHP, aq. 70%) in high yields. Thus, an efficient, economic and experimentally simple protocol for dethioacetalization has been demonstrated.
β¦ LIBER β¦
Asymmetric oxidation of 1,3-dithiolanes. A route to the optical resolution of carbonyl compounds
β Scribed by O Bortolini; F Di Furia; G Licini; G Modena; M Rossi
- Book ID
- 104219524
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 188 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The asymmetric oxidation (t-Bu02H, Ti(OPr-t)4, DET) of a series of 1,3-dithiolanes was carried out to produce the corresponding S-oxides with high chemical and optical yields.
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