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Photorearrangement of 7-methylene-8-chloromethylenecycloocta-1,3,5-triene

โœ Scribed by Elix, J. A.; Sargent, Melvyn V.; Sondhheimer, Franz.


Book ID
127059229
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
381 KB
Volume
89
Category
Article
ISSN
0002-7863

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Photorearrangements of 1-methoxy-8-pheny
โœ F.A.L. Anet; Duncan P. Mullis ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 170 KB

Recently Pappas and Pappas (1) have shown that acetylenes add photochemically to methoxy-p-benzoquinone to give derivatives of bicyclo[4.2.0]octa-3,7-diene-2,5-dione, The exact structure (Ia or Ib) of the phenylacetylene-methoxybenzoquinone adduct I was not determined. We have now found that this ad