𝔖 Bobbio Scriptorium
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Valenzisomerisierungen der7,8-bis(phosphano)cycloocta-1,3,5-triene

✍ Scribed by G Märkl; B Alig; E Eckl


Book ID
104226906
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
209 KB
Volume
26
Category
Article
ISSN
0040-4039

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Phosphaalkynes 2 and electron-deficient alkynes 11 readily configuration of the phophatricyclodecadienes 12. In solution the tricyclodecadienes 13 are prone to facile cycloreversion react in a [4 + 2] cycloaddition process with 5,8bis(trimethylsilyl)cycloocta-1,3,6-triene (8) in its bicyclic form yi

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The low-lying intmvalence and Rydberg excited states of cyclohepta-lJ,Striene and cycloocta-1,3,5,7-tetraene, accessed by one-and twc-photon absorption, have been investigated at ab initio level by utilizing RPA vertical transition energies and amplitudes. The nature of the first valence-like excite