Photophysical Properties of (O 2 ( 1 Δ g )) 2 and O 2 ( 1 ) in Solution Phase
✍ Scribed by Chou, Pi-Tai; Chen, Youn-Chan; Wei, Ching-Yen; Chen, Shu-Juan; Lu, Hui-Ling; Wei, Tai-Huei
- Book ID
- 125896596
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 208 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +
molecules from a discharge have been analyzed by the emission of the infrared atmospheric (0.0) bancfat 12700 A and by the emission of the atmospheric (0,O) band at 7619 A due to the energy pooling reaction ## 202(1Agj -+02('Cs) + 02(%;) . Particular rate constants for the deactivation of 02(1 A