Photophysical, photochemical, and electrochemical properties of mononuclear and dinuclear ruthenium(II) complexes containing 2,2'-bipyridine and the 3,5-bis(pyridin-2-yl)-1,2,4-triazolate ion
โ Scribed by Barigelletti, Francesco; De Cola, Luisa; Balzani, Vincenzo; Hage, Ronald; Haasnoot, Jaap G.; Reedijk, Jan; Vos, Johannes G.
- Book ID
- 126427382
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 933 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
The temperature dependence of the emission lifetime of the series of complexes Ru(bpy),(4,4'-dpb): ? (bpy = 2,2'-bipyridine, 4,4'-dpb = 4,4'-diphenyL2,2'-bipyridine) has been studied in propionitrile/butyronitrile (4:5 u/u) solutions in the range 90-293 K. The obtained photophysical parameters show
Reactions of [RhClL] (L,=diolefin or (CO)(PPh,)) with the deprotonated form of the ligand 3,5bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh&)(bpt)]. Cationic, mono-and dinuclear species of formulae [Rh&.)(Hbpt)]+, [{Rhb}\*(bpt)]+ and [{Rh&.}@bpt)]\*+, where b=diolefi